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Measuring Hydrogen
02. Mai 2024
The efficient use of hydrogen blended into natural gas requires the right measurement technology, and can correlative instrumentation can help
Interest in hydrogen as an energy carrier has been steadily increasing over the last decade, with many studies being performed into its generation, transport, storage, and use. The reason for the interest is clear; hydrogen is a carbon-free fuel that can be produced with renewable energy and combusted like natural gas. However, the physical properties of hydrogen are considerably different to those of natural gas, which prevents it from being a direct replacement. The blending of hydrogen into existing natural gas pipelines (typically up to 20% by volume) is being investigated in numerous countries as a way to reduce CO2 emissions. This solution has the advantages of continued use of the existing infrastructure (transport, distribution and end-use), and resilience to variations in hydrogen production and availability.
Hydrogen
Blending
The main issues with hydrogen blending result from the aforementioned
differences between hydrogen and natural gas. Hydrogen has a higher flame
temperature, considerably higher flame speed and lower air requirement for
combustion, meaning that substantial efficiency gains can be achieved by
optimizing combustion processes for gas composition. Furthermore, the
volumetric energy content of hydrogen is approximately one third of that of
natural gas. As such, knowledge of the hydrogen content is not only key to
efficiency gains for combustion processes, but also fair billing of gas
consumption. With hydrogen injection and blending likely distributed throughout
the network, this means that not only large temporal, but also spatial
variability in hydrogen content can be expected.
Measurement
In this scenario, the need for determining the hydrogen content is clear,
however the requirements on the instrumentation and sensors are quite high.
Reference level instruments for gas quality determination, such as gas
chromatographs, are often too expensive, complicated, or slow for many
end-users. This has opened the door for other specialized instruments,
employing e.g. correlative principles, which infer (or correlate) a property of
the gas mixture based on the measurement of one or more other gas properties
such as the thermal conductivity, heat capacity, speed of sound or density. For
applications involving hydrogen correlative measurements function exceedingly
well, as the physical properties of hydrogen differ greatly from those of
natural gas. Correlative measuring instruments often have surprising benefits:
they seldom require recalibration, are nearly immune to poisoning, absolute
measurement accuracy is not tied to gas concentration, and they can be employed
for virtually any concentration range.
The gasQS static from Mems AG operates on the principle of thermal conductivity
The gasQS static from Mems AG is an example of a correlative measuring instrument that operates on the principle of thermal conductivity measurements. Through laboratory calibration the thermal conductivity is equated to the concentration of hydrogen in the gas, which is returned as a 4-20 mA signal. The static is employed in the regulation of gas motors (ignition timing) and burners (power and air flow regulation), in hydrogen blending stations and for tracing hydrogen concentrations through distribution networks. The fast reaction time (T90 of 2 seconds), direct pipeline connection and no venting of gas are particularly valued characteristics for these applications.
Correlative measuring instruments can be used for most concentration ranges